A Study on the Reactivity of WCl6–e––Al–CH2Cl2 with the Silicon-Containing Dienes

摘要

Although until the late 1980s very little information on effective metathesis conversion of organosilicon compounds had been reported, the use of molybdenum (Schrock) catalyst and ruthenium (Grubbs) carbene complexes as catalysts tolerating functional groups in substrates, have opened new synthetic opportunities in organosilicon chemistry. Silicon containing dienes undergo two types of metathetical transformation.