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Fast Pyrolysis of Pine Wood: The Influence of Process Parameters on the Quality and the Quantity of the Pyrolysis Oil

机译:松木的快速热解:过程参数对热解油质量和量的影响

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In this research fast pyrolysis of pine saw dust was studied to establish the effect of the process parameters such as pyrolysis temperature, feed rate and residence time on conversion and the quality of the products on bench scale. Fast pyrolysis experiments carried out in a bubbling fluid bed reactor heated externally.100g of PSD was pyrolyzed at 400C, 500C, and 600C. The highest conversion yields of liquid, solid and gas products (at respective pyrolysis temperatures) were 56% (500°C), 20%(400°C) and 58% (600°C). General characteristics of bio-oil such as viscosity, Karl Fischer water content, ash, C, H, O, N and metals were determined.13C NMR spectroscopy was used for the determination of the functional groups present in the oil. Separation and quantification of the gaseous products such as H2, CO, CO2 and C1-C6 range hydrocarbons were performed by gas chromatography. Char was analyzed for metals and ash content.
机译:在这项研究中,研究了松树锯尘的快速解析,以建立过程参数如热解温,进料速率和停留时间的转化率和替补秤上的质量。在外部加热的液体床反应器中进行的快速热解实验在400℃,500℃和60℃下热解。最高的液体,固体和天然气产品(在各自的热解温度下)的转化产率为56%(500℃),20%(400℃)和58%(600℃)。确定生物油的一般特征,如粘度,卡尔费斯含水含量,灰,C,H,O,N和金属.13C NMR光谱用于测定油中存在的官能团。通过气相色谱法进行H 2,CO,CO 2和C1-C6范围烃等气体产品的分离和定量。分析了金属和灰分含量的焦炭。

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