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NONLINEAR ANALYSIS OF PFR – SEPARATION – RECYCLE SYSTEMS COUPLING EXOTHERMIC AND ENDOTHERMIC REACTIONS

机译:PFR分离 - 循环系统耦合放热和吸热反应的非线性分析

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Performing endothermic and exothermic chemical reactions in a single unit offers several advantages. It guarantees in general increased thermal efficiency and, for reversible chemical reactions, can lead to increased reactor equilibrium conversion and increased reaction rate due to equilibrium displacement . As a result, energy savings and reduced reactor size are achieved. Some examples demonstrating the effectiveness of this idea are in situ hydrogen combustion in oxidative dehydrogenation coupling propane combustion and endothermic thermal cracking of propane to ethylene and propylene , coupling methane steam reforming with catalytic oxidation of methane in partial oxidation reactors.
机译:在单个单元中进行吸热和放热化学反应提供了几个优点。它的保证通常增加热效率,并且对于可逆化学反应,可以导致反应器平衡转化增加和由于平衡位移引起的反应速率增加。结果,实现了能量节约和降低的反应器尺寸。展示该思想的有效性的一些例子在氧化脱氢偶联丙烷燃烧中原位氢气燃烧,丙烷的吸热热裂缝与乙烯和丙烯,偶联甲烷蒸汽重整在部分氧化反应器中溶液催化氧化。

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