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Surfactant-Based Fluid-Loss Pills for ZnBr2-Based High-Density Completion Fluids and High-Temperature Applications

机译:基于表面活性剂的流体损失丸,用于ZnBr2的高密度完成流体和高温应用

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Excessive loss of high-density brines into the formation has always been a major concern during completion operations, since it is uneconomical and leads to formation damage and well control issues. A viscoelastic surfactant (VES) system was introduced as an alternative for polymers because of high-temperature instability, incompatibility problems, and the necessity of acid cleanup for the polymer-based system. However, past literature documented that VES systems were limited to only CaCl2/CaBr2 brines due to the negative effect of ZnBr2 solutions on the surfactant's ability to form gel which limits the applicable density for past fluid-loss pills. This paper introduces improved fluid technology that uses nanoparticles and new low molecular weight surfactants to effectively control fluid-losses for high-density brine that contains ZnBr2 at high temperature application. Laboratory studies were conducted to examine the effect of the VES system on controlling leak-off rate using a HP/HT fluid-loss cell. The apparent viscosity of the VES solution was measured as a function of shear rate and temperature (up to 300°F). Based on experimental results leak-off of surfactant based fluid is controlled by the elastic structure of the surfactant micelles. The strong elastic structure of gel will not deform to pass through the pores, it will plug this pores and eliminate any flow of the solution. Therefore, surfactant-based pill developed long-term stability as it tested for 7 days with a noticeable decrease in the leak-off rate with time. Optimum surfactant concentration does not depend on the brine composition or formation permeability but it was mainly dependent on temperature. A breaker based on mineral oil caused a smooth viscosity decline while a breaker based on mutual solvent had a rapid viscosity decline. For mutual solvent, viscosity was instantaneously reduced by 50 to 90% depending on brine composition, surfactant concentration and temperature. However, temperature has most significant effect.
机译:在完成操作期间,高密度盐水的过度损失始终是一个主要问题,因为它是不经济的并且导致形成损害和控制问题。由于高温不稳定性,不相容性问题和基于聚合物的系统的酸性清除,将粘弹性表面活性剂(Ves)系统作为聚合物的替代品引入。然而,由于ZnBr2溶液对表面活性剂形成凝胶的能力的负面影响,VES系统仅涉及仅限VES系统仅限于CACL2 / CABR2盐水,这限制了过去的流体损失药丸的适用密度。本文介绍了利用纳米颗粒和新的低分子量表面活性剂的改进的流体技术,以有效地控制含有ZnBr2的高密度盐水的流体损失在高温下。进行实验室研究以检查VES系统对使用HP / HT流体损失细胞控制泄漏率的影响。测量VES溶液的表观粘度,为剪切速率和温度(最多300°F)。基于实验结果基于表面活性剂流体的泄漏由表面活性剂胶束的弹性结构控制。凝胶的强弹性结构不会使穿过毛孔的变形,它会堵塞这种孔并消除溶液的任何流动。因此,基于表面活性剂的丸显着的长期稳定性,因为它在泄漏率随时间泄漏率的明显减少测试7天。最佳表面活性剂浓度不依赖于盐水组合物或形成渗透性,但它主要取决于温度。基于矿物油的断路器引起了光滑的粘度下降,而基于相互溶剂的断路器具有快速的粘度下降。对于相互溶剂,取决于盐水组合物,表面活性剂浓度和温度,粘度瞬间降低50至90%。但是,温度具有最显着的影响。

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