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Conducting a Mercury Mass Balance at Petroleum Refineries

机译:在石油炼油厂进行水银质量平衡

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Flint Hills Resources, L.P. (FHR), which owns and operates a 300,000-barrel-per-day (bpd) petroleum refinery in Rosemount, Minnesota, has been working since 2000 to better understand and reduce the risk of mercury contamination to the environment from the refinery. FHR completed and submitted to the Minnesota Pollution Control Agency (MPCA), as part of the Voluntary Mercury Reduction Project, a mercury mass balance in 2000 with updates in 2004 that thoroughly sampled and analyzed inlet and outlet streams in the refinery. This balance identified the distribution of mercury in crude oil feed to the various refinery output streams such as fuel products, facility air emissions, wastes and water effluent. Unfortunately due to the complexity of the refinery operations, the chemical properties of mercury in crude oil, and inadequacy of mercury analysis methods at the time of the mass balance, FHR was unable to allocate all of the mercury coming in with the crude oil to finished products, waste streams, combustion sources or water discharges that leave the facility.
机译:Flint Hills资源,LP(FHR),其拥有并经营每天30万桶(BPD)石油炼油厂,Minnesota自2000年以来一直在工作,以更好地了解并降低汞污染的风险炼油厂。 FHR完成并提交明尼苏达污染管制局(MPCA),作为自愿水银减少项目的一部分,2000年的汞批量平衡,2004年的更新,炼油厂中的彻底采样和分析了入口和出口流。这种平衡确定了原油供给到各种炼油厂输出流,如燃料产品,设施空气排放,废水和水流口的分布。不幸的是,由于炼油厂的复杂性,原油中汞的化学性质,以及汞分析方法的不足,在质量平衡时,FHR无法分配与原油含有原油的所有汞产品,废物流,燃烧源或离开设施的排水。

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