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Broadcast Photonic Curing of Metallic Nanoparticle Films

机译:金属纳米粒子膜的广播光子固化

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摘要

A novel and industrially scalable technique is presented for curing metal nanoparticle based films in which an uncured film is made conductive by exposure to a brief, intense pulse of light from a xenon flash lamp. This technology heats and fuses the metal nanoparticles without significantly heating the substrate. Since the technique is broadcast by nature, no critically aligned optics are required. By nature of their high surface to mass ratio, high absorptivity, poor thermal conductivity, and low thermal mass, the nanoparticles are heated by the pulsed light source without significantly heating the substrate or other thermally sensitive components. This allows a complex pattern to be instantly cured even on low temperature substrates. Data from both silver and copper based films are presented. Sheet resistances as low as 20 mΩ/□ and resistivities as low as 4X bulk have been attained with silver. Sheet resistances as low as 150 mΩ/□ and resistivities as low as 40X bulk have been attained with copper. Typical substrates are cellulose and PET and typical films are 0.5-5 microns thick. In addition to silver, this technology enables the printing of copper conductive patterns with high speed printing techniques as the short time of heating fuses the particles before they have the opportunity to significantly oxidize. Thus, no reducing or inert atmosphere is required to cure the film and attain high conductivities.
机译:提出了一种新颖的和工业上可伸缩的技术,用于固化金属纳米粒子的薄膜,其中通过暴露于来自氙闪光灯的简要突出的光进行导电的未固化膜。该技术加热并熔化金属纳米颗粒而不显着加热基材。由于该技术由自然播出,因此不需要批判性对齐的光学器件。本质上,其高度的质量比,高吸收性,导热性差和低热质量,纳米颗粒被脉冲光源加热,而不显着加热基板或其他热敏组分。即使在低温基板上,这允许复杂的图案即使在低温基板上立即固化。提出了银和铜薄膜的数据。薄层电阻低至20mΩ/□,电阻低至4倍散装。铜的薄层电阻低至150mΩ/□和低至40倍散装的电阻。典型的基材是纤维素,PET和典型的膜厚度为0.5-5微米。除了银,该技术还可以通过高速印刷技术打印铜导电图案,因为在加热熔化颗粒之前,在有机会显着氧化之前,可以使用高速印刷技术。因此,不需要减少或惰性气氛来固化薄膜并获得高导体。

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