Constrainment Effects of Interleaved Organic Molecules into Layered Double Hydroxides

摘要

Incorporation and subsequent stabilization of organic molecules into layered double hydroxide are investigated.Through two types of hybrid materials,organic dyes and aniline-based monomers interleaved between LDH materials of cation composition ZN_2Al and Cu_2Cr respectively,it is shown that the effect of the constrainment is revealed by the interactions different according to the molecule size and stacking as exemplified by dye molecules,orange 6 and green 25 acids and two aniline-based monomers,m-amino-4-benzenesulfonic and 3-aniline-l-propanesulfonic acids.