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Dealing With H2S in Heavy-Oil Thermal Projects

机译:在重油热项目中处理H2S

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摘要

There is an abundance of natural gas being discovered and produced that is slightly sour.According to a US Department of the Environment(DOE)survey that includes Canada,about 80%of current and new gas has a hydrogen sulphide(H2S)concentration of 1%or less.Of course,this must be treated to remove the H2S to meet sales gas specifications.For small scale(less than 50-100 kg)and large scale(greater than 20 tonne/d)of equivalent sulphur,current technologies appear reasonable.Conversely,for intermediate range (0.1-20 tonne/d)equivalent sulphur,current technology has proven to have high capital and/or operating costs and some processes are difficult to operate.Therefore,there is a need for an intermediate scale(0.1 to 20 tonne/d)process with lower capital and operating cost than those currently available.The applications of such a process range from the removal of H2S from acid gas at low pressure produced from the amine process to high pressure raw sour gas. There are additional challenges from sour gas associated with heavy oil thermal projects in that it is at low pressure and contains substantial C7+.The elemental sulphur produced should be of sales grade quality such that the handling of the product can fit into the existing sulphur infrastructure and sold into existing markets. Otherwise,disposal of the product becomes costly and in some cases becomes another environmental problem.
机译:正在发现和生产的丰富天然气,略微酸。根据美国的环境部(DOE)调查,包括加拿大的调查,约80%的当前和新的气体具有硫化氢(H2S)浓度为1 %或更少。当然,必须处理这一点以删除H2S以满足销售气体规格。对于小规模(小于50-100千克)和大规模(大于20吨/吨)的等效硫,目前的技术出现合理。对于中间范围(0.1-20吨/ d)当量硫,现已证明具有高资本和/或运营成本,并且一些流程难以运行。因此,需要中间规模( 0.1至20吨/ d)资本和运营成本低于目前可用的工序。这种过程的应用范围从从胺过程中的低压下除去H2S从酸气中的高压原料酸气体。与重油热项目相关的酸性气体存在额外的挑战,因为它处于低压并含有大量的C7 +。产生的元素硫应该是销售级别的质量,使得产品的处理可以适合现有的硫基础设施和硫磺基础设施和销售为现有市场。否则,产品处理成本高昂,在某些情况下成为另一个环境问题。

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