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Effects of Asphaltene Content and Solvent Concentration on Heavy-Oil Viscosity

机译:沥青质含量和溶剂浓度对重油粘度的影响

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During a solvent-based heavy oil recovery process, significant viscosity reduction is achieved through sufficient solvent dissolution and possible asphaltene precipitation. In the second viscosity reduction mechanism, the heavy oil is in-situ upgraded as the asphaltene content in the produced heavy oil is greatly lowered. In this paper, the respective and synergistic effects of asphaltene content and solvent concentration on heavy oil viscosity are studied by measuring viscosities of heavy oil samples with different asphaltene contents and/or solvent concentrations. More specifically, a deasphalted heavy oil sample is obtained by using the standard ASTM method to extract asphaltenes from a crude heavy oil. Then reconstituted heavy oil sample is prepared by adding the extracted asphaltenes into the deasphalted heavy oil at a different asphaltene content each time and its corresponding viscosity is measured at the atmospheric pressure. It is found that the viscosity of such prepared heavy oil is sensitive to the asphaltene content. In particular, the viscosity of the deasphalted heavy oil is reduced by 13.7 times in comparison with that of the original heavy oil at T=23.9 °C. This indicates that high asphaltene content results in high viscosity of the heavy oil. On the other hand, the viscosities of propane-saturated heavy oil samples with different asphaltene contents are measured at high pressures. As the equilibrium propane concentration reaches certain value, the viscosity of the crude heavy oil-propane system is reduced by almost two orders. This result shows that solvent dissolution plays a dominant role in heavy oil viscosity reduction. When the equilibrium propane concentration is high enough, all the three reconstituted heavy oil-propane systems have extremely low viscosities. In this case, effect of asphaltene content on heavy oil viscosity becomes negligible.
机译:在基于溶剂的重油回收过程中,通过足够的溶剂溶解和可能的沥青质沉淀来实现显着的粘度降低。在第二粘度降低机制中,重油是原位升级,因为产生的重油中的沥青质含量大大降低。在本文中,通过测量具有不同沥青质含量和/或溶剂浓度的重油样品的粘度来研究沥青质含量和溶剂浓度对重油粘度的各自和协同作用。更具体地,通过使用标准的ASTM方法获得脱沥青重油样品以从粗重油中提取沥青质。然后通过在每次在不同的沥青质含量在不同的沥青质含量下加入脱沥青重油中,在不同的沥青质含量在大气压下测量其相应的粘度来制备重构的重油样品。发现这种制备的重油的粘度对沥青质含量敏感。特别地,与T = 23.9℃的原始重油的粘度降低了13.7倍。这表明高沥青质含量导致重油的高粘度。另一方面,在高压下测量具有不同沥青质含量的丙烷饱和重油样品的粘度。随着均衡丙烷浓度达到某些值,粗产油丙烷系统的粘度几乎减少了几乎两个订单。该结果表明,溶剂溶解在重油粘度降低中发挥着显性作用。当平衡丙烷浓度足够高时,所有三个重构的重油丙烷系统具有极低的粘度。在这种情况下,沥青质含量对重油粘度的影响变得可忽略不计。

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