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A Flow Assurance Study on Elemental Sulfur Deposition in Sour Gas Wells

机译:酸气井井元素硫沉积的流量保证研究

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This paper summarizes a flow assurance study for elemental sulfur deposition in the tubing for the Chuandongbei Gas Project (CDB), a greenfield sour dry gas development project in Sichuan, China. The project is a co-venture of Chevron and China National Petroleum Company (CNPC). The development contains several fields, all containing dry gas with 8-17% H2S, and 8-10% CO2. Elemental Sulfur (S8) dissolved in the gas may precipitate in both the near-well reservoir region, and tubing, within the pressure and temperature range predicted for gas well flow in the fields. The precipitate may form gas flow restrictions. An offset operator producing gas from the same reservoir interval and having similar composition has reported flow problems attributed to S8. This study focused on the prediction of S8 deposition in the tubing, during both production and shut-in periods. Numerical transient well pressure and temperature modeling with the OLGA wax deposition module was used to predict precipitation and deposition of S8 in the tubing. Presently, no other S8 deposition model is available. The model estimates the pressure and temperature gradient between the bulk fluid and tubing wall, and molecular diffusion rates through the laminar sub-layer of the fluid velocity profile. An S8 phase equilibruium model calibrated by measured phase behavior from a laboratory synthetic gas having the composition of CDB field measured surface gases was used to generate the S8 phase diagram. The study indicates that shut-in periods present the greatest S8 deposition risk: suspended sulfur precipitate accumulates at bottomhole during shut-in periods, possibly forming a flow restriction. Mitigation through solvent treatment applied after shut-in periods is therefore planned. S8 deposition on tubing walls during flow periods was found to present relatively low flow assurance risk. This study also provides operational design recommendations for well start up, sustained flow, and shut-in periods, as well as flow assurance mitigation design.
机译:本文总结了川北煤气项目(CDB)管中元素硫沉积的流动保证研究,这是中国四川的绿地酸性干气开发项目。该项目是雪佛龙和中国石油公司(CNPC)的合资企业。该开发含有几个田地,含有8-17%H2S和8-10%CO 2的干气。溶解在气体中的元素硫(S8)可以在近孔储层区域和管道中沉淀,在压力和温度范围内预测的气体井在田地中流动。沉淀物可以形成气流限制。从相同的储层间隔产生气体并具有类似的组合物的偏移操作员已经报告了归因于S8的流量问题。该研究专注于在生产和关闭时段期间预测管中的S8沉积。使用OLGA蜡沉积模块的数值瞬态孔压力和温度建模用于预测管道中S8的沉淀和沉积。目前,没有其他S8沉积模型可用。该模型估计通过流体速度分布的层状子层的散装流体和管壁之间的压力和温度梯度,以及分子扩散速率。通过从具有CDB场测量的表面气体组成的实验室合成气体的测量相行为校准的S8相平衡模型用于产生S8相图。该研究表明,关闭时期呈现最大的S8沉积风险:悬浮的硫沉淀在关闭期间在底部累积,可能形成流动限制。因此,计划通过溶剂处理减轻溶剂处理。发现在流动时段期间的管壁上的S8沉积出现相对低的流量保证风险。本研究还提供了用于良好启动,持续的流动和关闭期的操作设计建议,以及流动保证缓解设计。

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