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Acid Treatments in High Temperature Dolomitic Carbonate Reservoirs Using Emulsified Acids: A Coreflood Study

机译:使用乳化酸的高温白云岩碳酸盐储存器中的酸性处理:核心研究

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Acid treatments in deep wells drilled in carbonate reservoirs represent a challenge to the oil industry. Emulsified acid can be used in matrix acidizing and acid fracturing treatments. The delayed nature of emulsified acid is useful in creating deep wormholes and etched fracture surfaces. The high temperature of deep wells requires a special formulation of emulsified acid that is stable and effective at such high temperatures. The main objective of the present work is to study the performance of emulsified acid in stimulating high temperature deep wells drilled in dolomitic carbonate reservoirs. A coreflood study was conducted using dolomite cores, which had dimensions of 1.5 in. diameter and 6 in. length. The initial permeability of the dolomite cores used in the current study ranged from 1.6 to 20.9 md. Emulsified acid systems were formulated at 0.7 acid volume fraction, 1.0 vol% emulsifier, and 15 wt% HCl concentration. Coreflood experiments were performed at a temperature of 300°F, at injection rates range from 0.5 to 10 cm~3/min until acid breakthrough the core. Samples of the effluent fluids were collected and analyzed using ICP to measure the calcium and magnesium concentrations. All cores were CAT scanned before acid treatment to study the presence of vugs, and after acid injection to study the characteristics of the generated wormhole. The results show that the emulsified acid created wormholes in dolomite cores, resulting in better treatment outcome. For emulsified acid injection rates in the range from 0.5 to 10 cm~3/min, the volume of emulsified acid injected to achieve breakthrough increased with the increase in the emulsified acid injection rate. Also, there was no optimum injection rate for the injection rate range studied (0.5 to 10 cm~3/min). The number and size of the created wormholes was function of the injection rate of emulsified acid. This paper summarizes the results obtained and recommends the use of emulsified acid systems for field applications with dolomite reservoirs.
机译:在碳酸盐储层中钻的深井中的酸治疗代表了石油工业的挑战。乳化酸可用于基质酸化和酸性压裂处理。乳化酸的延迟性质可用于制造深虫洞和蚀刻的裂缝表面。深井的高温需要特殊配方的乳化酸,其在这种高温下稳定而有效。本作研究的主要目的是研究乳化酸在刺激白云岩碳酸盐储层钻井的高温深井中的性能。使用白云石核心进行了核心研究,该研究具有1.5英寸的尺寸。直径和6英寸。长度。目前研究中使用的白云石芯的初始渗透率范围为1.6至20.9 md。将乳化酸体系在0.7酸体积级分,1.0体积乳化剂和15wt%HCl浓度下配制。 CoreFlood实验在300°F的温度下进行,注射速率范围为0.5至10cm〜3 / min,直至酸突破核心。使用ICP收集并分析污水流体的样品以测量钙和镁浓度。所有核心都是酸治疗前扫描的猫,以研究Vugs的存在,并在酸注射后研究产生的虫洞的特性。结果表明,乳化酸在白云石核心中产生虫洞,导致更好的治疗结果。对于乳化酸注射率,范围为0.5至10cm〜3 / min,注入乳化酸的体积随着乳化酸注射速率的增加而增加。此外,研究的注射速率范围没有最佳注射速率(0.5至10cm〜3 / min)。所产生的虫洞的数量和尺寸是乳化酸的注射速率的作用。本文总结了获得的结果,并建议使用乳化酸系统进行白云岩储层的现场应用。

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