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Core-shell Polyacrylate Latex Containing Silicon in Shell

机译:核 - 壳聚丙烯酸酯胶乳含有硅壳

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Core-shell lattices are importance in coatings, adhesives and many other areas. Polysiloxane possesses a number of special properties, such as high flexibility, good weather resistance and excellent thermal stability. Thus, it is an excellent material for the modification of polyacrylates. However, there are only a few reports on siloxane, especially, polysiloxane in shell phase. In this work, a difunctional monomer, γ-Methacryloxypropyl trimethoxy silane (WD-70) was used to prepare the core-shell polyacrylate latex containing silicon in the shell. The polymerization condition was discussed in detail. The components of the latex containing silicon were determined by FT-IR and DSC. The morphology of the latex particles was investigated by transmission electron microscopy (TEM). The water contact angles were determined by Wilhelmy method.
机译:核心壳格子在涂料,粘合剂和许多其他区域的重要性。聚硅氧烷具有许多特殊性质,如高柔韧性,耐候性好,热稳定性优异。因此,它是用于改性聚丙烯酸酯的优异材料。然而,在硅氧烷中只有少数报道,特别是壳相中的聚硅氧烷。在这项工作中,使用双官能单体,γ-甲基丙烯酰氧基二甲氧基硅烷(WD-70)在壳中制备含有硅的核 - 壳聚丙烯酸酯胶乳。详细讨论了聚合条件。含胶乳的组分通过FT-IR和DSC测定。通过透射电子显微镜(TEM)研究了胶乳颗粒的形态。通过WILHELMY方法确定水接触角。

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