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Modeling of a Direct Carbon Molten Carbonate Fuel Cell with Porous Bed Electrodes

机译:多孔床电极直接碳熔融碳酸盐燃料电池建模

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Carbon may be reacted directly, without gasification, in a molten carbonate fuel cell. The cathode reaction is 2CO_2 + O_2 + 4e- => 2CO3=, while the anode reaction can be either C + 2CO_3= => 3CO_2 + 4e- or 2C + CO_3= => 3CO + 2e-.The direct carbon fuel cell has an advantage over fuel cells using coal-derived synthesis gas in that it provides better overall efficiency and reduces equipment requirements. For solid carbon fuel the molten carbonate cell has an advantage over solid oxide fuel cells in that the anode produces more CO_2 and less CO than chemical equilibrium predicts. Also, the liquid electrolyte provides a means for transporting the solid carbon.
机译:碳可以在熔融的碳酸盐燃料电池中直接反应,无需气化。阴极反应是2CO_2 + O_2 + 4E- => 2CO3 =,而阳极反应可以是C + 2CO_3 => 3CO_2 + 4E-或2C + CO_3 => 3CO + 2E-。直接碳燃料电池具有使用燃煤合成气体的燃料电池的优势,因为它提供更好的整体效率并降低设备要求。对于固体碳燃料,熔融碳酸盐电池在固体氧化物燃料电池中具有优点,因为阳极产生更多的CO_2和较少的CO,而不是化学平衡预测。而且,液体电解质提供用于输送固体碳的装置。

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