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ADVANCED ARTIFICIAL DEACTIVATION OF FCC CATALYSTS

机译:FCC催化剂的先进人工失活

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The worldwide energy management nowadays demands a more sophisticated utilization of the existing energy sources. The refineries are significantly affected by these energy saving policies requiring improvement/modification of existing or development of new/alternative refining processes. One solution is to upgrade more and more of heavier or residual fractions into lighter desirable distillates via catalytic cracking. However, the residual cracking poses numerous problems for the oil companies and the catalyst manufacturers. The increasing portion of larger molecules/compounds containing heteroatoms and metal contaminants in fractions of increasing boiling point mainly accounts for the difficulties in processing heavy oils. Thus, problems associated with decreased catalyst stability, activity and selectivity are becoming more often and more serious during processing residual FCC feeds, demanding new FCC catalyst technologies [1]. A more detailed knowledge of the deactivation mechanisms could significantly facilitate manufacturing of improved, metal-tolerant FCC catalysts. Moreover, a most realistic and accurate laboratory procedure for the evaluation of such improved FCC catalysts is essential. As a result, one of the biggest challenges in FCC research field is to first simulate how the FCC catalyst is deactivated in a commercial FCC unit and then evaluate its performance in lab-scale testing [2]. The scope of the present study is to investigate the effects of the deposited metals and their oxidation state during laboratory deactivation on the final properties of the deactivated samples.
机译:当今全球能源管理需要更复杂的现有能源利用。炼油厂受到这些节能政策的显着影响,要求改进/修改现有或开发新/替代炼油过程。一种解决方案是通过催化裂化将越来越多的更柔和或残留的馏分提升到更轻的馏出物中。然而,剩余开裂为石油公司和催化剂制造商带来了许多问题。含有杂原子和金属污染物的较大分子/化合物的增加部分主要占加工重油中的困难。因此,在加工残留的FCC饲料中,催化剂稳定性,活性和选择性降低的问题越来越严重,要求新的FCC催化剂技术[1]。更详细地了解失活机制,可以显着促进改进的金属耐性FCC催化剂的制造。此外,用于评估这种改进的FCC催化剂的最逼真和准确的实验室程序是必不可少的。因此,FCC研究领域的最大挑战之一是首先模拟FCC催化剂如何在商业FCC单元中停用,然后评估其在实验室规模测试中的性能[2]。本研究的范围是研究沉积金属及其氧化态在实验室失活对失活样品的最终性质期间的影响。

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