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THE METALOZON PROCESS FOR THE RECOVERY AND RECYCLING OF PRECIOUS METALS

机译:金属酶的回收和回收贵金属的过程

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The leaching characteristics of Cu, Ni, Ag, Au, Pd, Rd and Pt with aqueous ozone were investigated. The Metalozon process consists basically of three consecutive steps: 1) Cu and Ni are recovered from a first step by leaching in O{sub}2/H{sub}2SO{sub}4.2) Ag is leached in O{sub}2/O{sub}3/H{sub}2SO{sub}4.3) Au and Pd are recovered by leaching in O{sub}2/O{sub}3/H{sup}+ in presence of dilute Cl{sup}-(~0.1M). Rh and R remain in the final residue. The main characteristics are: a) All steps can be carried out at ambient temperature and normal pressure or moderate overpressure; b) Kinetics are basically controlled by mass transfer; c) The main by-product of the steps 2 and 3 is O{sub}2 which is recycled to step I; and d) Recovery of the metals by electrolysis or by HI reduction regenerates the acidity consumed. The process can be cost-effective and of very low environmental impact for a wide range of raw materials: Including radiographic plates, gold concentrates, anode slimes from copper electro refining, electronic scrap, etc. Laboratory-scale results on these raw materials are reported.
机译:研究了Cu,Ni,Ag,Au,Pd,Rd和pt与臭氧水溶液的浸出特性。金属酶过程基本上由三个连续步骤组成:1)Cu和Ni通过在o {sub} 2的{sub} 2 / h {sub} 2so {sub} 4.2)中从第一步中恢复。在o {sub} 2 /中浸出o {sub} 3 / h {sub} 2so {sub} 4.3)通过在稀释cl {sup}的情况下浸出在o {sub} 2 / o} 3 / h {sup} +中恢复au和pd。 (〜0.1米)。 RH和R留在最终残留物中。主要特点是:a)可以在环境温度和常压或中度压力下进行所有步骤; b)动力学基本上由传质控制; c)步骤2和3的主要副产物是o {sub} 2,其再循环到步骤i; D)通过电解回收金属或通过HI降低再生消耗的酸度。该过程可具有成本效益,对广泛的原材料进行环境影响非常低:包括射线照相板,金浓缩物,来自铜电器精炼,电子废料等的阳极倍数。实验室级结果据报道这些原料的结果。

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