HYDROGEN KINETIC ISOTOPE EFFECTS IN THE STUDIES OF THE MECHANISM OF ACTION OF L-TYROSINE PHENOL LYASE

机译：氢动力学同位素在L-酪氨酸苯酚苯酚酶的作用机理研究中的作用

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The kinetic and solvent isotope effects have been determined in the reaction of decomposition of L-tyrosine catalyzed by enzyme TPL (EC 4.1.99.2). The numerical values of isotope effects were obtained using non competitive and competitive combined with internal radioactive standard methods.

机译：在酶TPL（EC 4.1.99.2）催化的L-酪氨酸分解的反应中已经确定了动力学和溶剂同位素效应。使用不竞争力和竞争结合与内部放射性标准方法进行同位素效应的数值。

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《International Symposium on the Synthesis and Applications of Isotopes and Isotopically Labelled Compounds》|2004年||共4页
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Wojciech Augustyniak; Ryszard Kanski; Marianna Kanska;
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原文格式 PDF
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中图分类 O615.2-532;
关键词
Deuterium; enzyme; isotope effects; L-tyrosine; tritium;

机译：氘;酶;同位素效应;L-酪氨酸;氚;

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1. Laboratory Studies of Carbon Kinetic Isotope Effects on the Production Mechanism of Particulate Phenolic Compounds Formed by Toluene Photooxidation: A Tool To Constrain Reaction Pathways [J] . Irei Satoshi, Rudolph Jochen, Huang Lin, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2015,第1期

机译：碳动力学同位素对甲苯光氧化形成微粒酚类化合物产生机理的实验室研究：限制反应途径的工具
2. Kinetics of the reaction of the heaviest hydrogen atom with H_2, the ~4Heμ + H_2 → ~4HeμH + H reaction: Experiments, accurate quantal calculations, and variational transition state theory, including kinetic isotope effects for a factor of 36.1 in isotopic mass [J] . Fleming D.G., Arseneau D.J., Sukhorukov O., The Journal of Chemical Physics . 2011,第18期

机译：最重氢原子与H_2，〜4Heμ+ H_2→〜4HeμH+ H反应的动力学：实验，精确的定量计算和变迁过渡态理论，包括同位素质量因数为36.1的动力学同位素效应
3. Kinetics of the reaction of the heaviest hydrogen atom with H_2, the ~4Heμ + H_2 → ~4HeμH + H reaction: Experiments, accurate quantal calculations, and variational transition state theory, including kinetic isotope effects for a factor of 36.1 in isotopic mass [J] . Fleming D.G., Arseneau D.J., Sukhorukov O., The Journal of Chemical Physics . 2011,第18期

机译：最重氢原子与H_2，〜4Heμ+ H_2→〜4HeμH+ H反应的动力学：实验，精确的定量计算和变迁过渡态理论，包括同位素质量因数为36.1的动力学同位素效应
4. HYDROGEN KINETIC ISOTOPE EFFECTS IN THE STUDIES OF THE MECHANISM OF ACTION OF L-TYROSINE PHENOL LYASE [C] . Wojciech Augustyniak, Ryszard Kanski, Marianna Kanska International Symposium on the Synthesis and Applications of Isotopes and Isotopically Labelled Compounds . 2004

机译：氢动力学同位素在L-酪氨酸苯酚苯酚酶的作用机理研究中的作用
5. Enthalpy and Entropy in Chemical Reactivity: I. Temperature Dependence of Secondary Deuterium Isotope Effects on the Acidity of Carboxylic Acids and Phenols, and a Rejection of any Inductive Contribution II. Kinetic and Mechanistic Studies of Reactions of Malonic Anhydrides III. Developing an ITC Method to Measure Heats of Proton Transfer [D] . Flach, Agnes 2012

机译：化学反应的焓和熵：I.次级氘同位素的温度依赖性对羧酸和苯酚酸度的影响，以及任何感应贡献的抑制II。丙二酸酐反应的动力学和机理研究。开发用于测量质子传递热的ITC方法
6. Evidence for the general base mechanism in carboxypeptidase A-catalyzed reactions: partitioning studies on nucleophiles and H2(18)O kinetic isotope effects. [O] . R Breslow, J Chin, D Hilvert, 1983

机译：羧肽酶A催化反应的一般基本机理的证据：亲核试剂的分区研究和H2（18）O动力学同位素效应。
7. Laboratory Studies on the Carbon Kinetic Isotope Effects on the Production Mechanism of Particulate Phenolic Compounds Formed by Toluene Photooxidation: A Tool to Constrain Reaction Pathways [O] . Irei, Satoshi, Rudolph, Jochen, Huang, Lin, 2014

机译：碳动力学同位素效应的实验室研究甲苯形成颗粒状酚类化合物的生成机理光氧化：限制反应途径的工具
8. Ab Initio Predictions and Experimental Confirmation of Large Tunneling Contributions to Rate Constants and Kinetic Isotope Effects for Hydrogen Atom Transfer Reactions [R] . Garrett, B. C., Truhlar, D. G., Bowman, J. M., 1986

机译：大型隧道对速率常数的贡献和氢原子转移反应的动力学同位素效应的从头算预测和实验证实

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HYDROGEN KINETIC ISOTOPE EFFECTS IN THE STUDIES OF THE MECHANISM OF ACTION OF L-TYROSINE PHENOL LYASE

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