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A STUDY OF THE DIFFUSION BRAZING PROCESS APPLIED TO THE SINGLE CRYSTAL SUPERALLOY CMSX-4

机译:应用于单晶超合金CMSX-4的扩散钎焊过程的研究

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The requirement for economic reconditioning of the latest ALSTOM gas turbine generation with Single Crystal (SX) superalloys has lead to the development of advanced repair processes such as Diffusion Brazing or Transient Liquid Phase bonding. Diffusion Brazing (DB) of conventionally cast polycrystalline turbine components has been carried out for many years but the requirement for this joining and repair technique to be applied to DS and SX superalloys has emerged only more recently. The main concern for the use of a braze-repair process for the more highly loaded SX components is the ability to guarantee sufficient thermal and mechanical integrity throughout the component lifetime. Such high strength braze joints in SX superalloys can be achieved by combining a brittle phase-free and high γ' content microstructure, while maintaining the crystallographical orientation of the SX parent material within the repair zone. Prior to the brazing process, a suitable crack surface preparation is essential, and this is achieved by the employment of specifically optimized Fluoride Ion Cleaning (FIC) process. This guarantees the complete removal of oxide from the crack surfaces and promotes the flow of the braze alloy for complete filling down to the crack tip. This paper presents the development of the DB process which has been specifically tailored for the repair of SX superalloys. The principles of the diffusion brazing process as applied to the CMSX-4 superalloy are discussed and the parameters which control the brazing kinetics are outlined. The optimization of the brazing heat treatment cycle will be presented. This paper also demonstrates the retention of the single crystal micro-structure in the repair zone, and demonstrates the test procedures developed to achieve the required thermal and mechanical integrity of braze repairs for application in SX gas turbine components.
机译:具有单晶(SX)高温合金的最新阿尔斯通燃气轮机发电的经济修复的要求导致高级修复过程,如扩散钎焊或瞬态液相键合。通常已经进行了常规铸造多晶涡轮机组件的扩散钎焊(DB),但是最近仅出现了对DS和SX高温合金的这种连接和修复技术的要求。主要关注使用钎焊修复过程更高负载的SX部件是能够在整个部件寿命中保证足够的热和机械完整性。通过组合脆性相和高γ'含量微观结构,可以通过组合脆性相和高γ'含量微观结构来实现这种高强度钎焊接头,同时保持修复区内Sx母材的晶形取向。在钎焊过程之前,合适的裂纹表面制备是必需的,这是通过采用特异性优化的氟离子清洁(FIC)方法来实现的。这保证了从裂缝表面完全除去氧化物,并促进钎焊合金的流动,以完全填充到裂缝尖端。本文介绍了DB过程的开发,专门针对SX超合金修复而定制。讨论了应用于CMSX-4高温合金的扩散钎焊过程的原理,并概述了控制钎焊动力学的参数。将呈现钎焊热处理循环的优化。本文还证明了修复区中单晶微结构的保留,并证明了在SX燃气轮机组件中应用钎焊修复所需的热和机械完整性的测试程序。

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