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Influence of Stabilizer Size and Chelation Strength on Iron Nanoparticle Oxidation

机译:稳定剂尺寸和螯合强度对铁纳米粒子氧化的影响

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Today, an increasing number of water contaminants are being identified and measured in our water sources. In addition, as the demand on water sources grows world‐wide, cities will have to increasingly rely on water recycling, water reuse, and impaired water sources. Traditional methods of water treatment are not always effective at removing smaller water contaminants, such as heavy metals and industrial chemicals, and the increasing number and concentrations of contaminants will be more and more challenging to eliminate. Iron, an abundant element found on Earth, can be used to synthesize different structured nanoparticles, including iron metal and iron oxide morphologies. In particular, iron core‐iron oxide shell particles are known to be used for treatment of contaminated groundwater. Based on this interest in iron‐based nanoparticles and cleaning water to allow for more reusable water, we are currently investigating the interactions between synthesized core‐shell iron nanoparticles and the different organic stabilizers used during synthesis. After synthesis, these stabilizer compounds are subsequently adsorbed to the surface of the iron nanoparticles and can affect the reactivity and lifetime of the nanoparticles in an aqueous environment.
机译:如今,正在在我们的水源中鉴定并测量越来越多的水污染物。此外,随着对水源的需求,全球增长,城市将不得不越来越依赖水循环,水再利用和水源受损。传统的水处理方法并不总是有效去除较小的水污染物,例如重金属和工业化学品,越来越多的污染物浓度和浓度越来越具有挑战性。铁,在地球上发现的丰富元素,可用于合成不同的结构化纳米粒子,包括铁金属和氧化铁形态。特别地,已知铁芯 - 氧化铁壳颗粒用于处理污染的地下水。基于对基于铁基纳米颗粒和清洁水的兴趣,允许更可重复使用的水,我们目前正在研究合成的核 - 壳铁纳米粒子和合成期间使用的不同有机稳定剂之间的相互作用。合成后,随后将这些稳定剂化合物吸附到铁纳米颗粒的表面上,并且可以影响纳米颗粒在水性环境中的反应性和寿命。

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