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Composition and Temperature Dependence of Microwave Conductivity of Potassium Germanate Glasses

机译:钾锗玻璃微波电导率的组成和温度依赖性

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The dependence of microwave conductivity, σ_(MW), on temperature (T) and alkali concentration has been studied for potassium germanate glass of composition Xk_2O·(1-x)GeO_2, 0.0023≤ x ≤ 0.247. From the empirical analysis, it is established that conduction at high frequency (f) and high T in these glasses is related to the conduction at low f and low T. The temperature dependence of σ_(MW) shows a weak thermal activation for all compositions as predicted by the model of jellyfish-like localized fluctuations of atoms in asymmetric double well potential configurations (ADWPC). The variation of σ_(MW) with alkali oxide concentration is however weaker than that observed at low T. It increases only by a factor of 2 for an increase from 0.23 to 25 mol% of K_2O at 1GHz.
机译:微波电导率,σ_(MW),温度(T)和碱浓度的依赖性已经研究了组合氧化钾XK_2O·(1-x)Geo_2,0.0023≤x≤0.247。从经验分析开始,在这些玻璃中的高频(F)和高T处的导通与低f和低T的导通相关。σ_(MW)的温度依赖性显示所有组合物的弱热激活如在不对称的双孔潜在配置(ADWPC)中的水母状局部化的模型预测的原子的局部波动。然而,具有碱氧化物浓度的σα(Mw)的变化比在低温下观察到的较弱。它仅增加2倍以增加0.23-25mol%的K_2O在1GHz。

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