THERMAL-RADIATION SYNTHESIS OF HYDRIDONITRIDES ON THE BASIS OF TITANIUM AND ZIRCONIUM

摘要

The results of systematic investigations of thermal-radiation processes in the system Ti_k(Zr_(1-k)N_x-H at irradiation by the accelerated electron beam are presented. The possibilities of thermal-radiation hydrogenation of nitrogen solid solutions in the bimetallic matrix titanium - zirconium were investigated. The parameters of the reaction of thermal-radiation synthesis in these systems were determined. The influence of a second metal on the post-radiation-stimulated interaction of the matrix with hydrogen was demonstrated. It was shown, that in the studied systems, the presence of a non-metallic sub-lattice, as well as of a second metal did not hinder the proceeding of radiation processes and the synthesis of HCP hydridonitrides of high hydrogen content (2.07-2.42 wt %).