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SPATIAL MODULATION OF ELECTRONIC STATES IN NANOSCOPIC PEAPODS

机译:纳米镜孔包装中电子态的空间调制

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A cryogenic scanning tunneling microscope (STM) has been used to perform atomic scale imaging and spectroscopy measurements of individual fullerene nanotube peapods. We show that the encapsulation of the C_(60) molecules does not modify the structure of the single-wall carbon nanotube (SWNT) cage yet strongly affects SWNTs' electronic properties. Spatially resolved measurements show that chains of C_(60) molecules induce periodic modifications of the unoccupied density of states in semiconducting SWNTs. These changes are caused by the coupling of the lowest unoccupied t_(1u) orbitals of the C_(60) molecules to the unoccupied SWNTs' one-dimensional electronic states.
机译:低温扫描隧穿显微镜(STM)已被用于对单个富勒烯纳米管孔板的原子尺度成像和光谱测量进行。我们表明C_(60)分子的封装不改变单壁碳纳米管(SWNT)笼的结构,但强烈影响SWNT的电子性质。空间分辨的测量显示C_(60)分子的链条诱导半导体SWNT中的状态的未占用密度的周期性修改。这些变化是由C_(60)分子的最低未占用T_(1U)轨道到未占用的SWNT的一维电子状态的耦合引起的。

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