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Synthesis And Development Of Metal Extractants

机译:金属萃取剂的合成与发育

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In synthesis and development of a metal extractants, yield and purity of the product are very important. There are various means of achieving this twin objective but the most attractive way is to gain the better understanding of the process and process parameter itself and then to improve and regulate them for optimum yield and purity. This approach needs quick and accurate methods for evaluating the design and operation of the process. A computer added simulation is suited for this purpose. This, in turn, needs a mathematical model, which is developed on the basis of sound theoretical knowledge about the system or on the extensive experimental data. Various reaction modeling approaches such as equilibrium constant method, Gibbs's free energy minimisation and reaction kinetics are discussed in this paper. Theoretical modeling approach needs to have reliable and accurate physical, chemical, thermodynamics and kinetic data. In the absence of these data, system can be model using black box approach. Various experimental methods are also outlined to achieve the desired objectives
机译:在合成和开发金属萃取剂的情况下,产品的产率和纯度非常重要。有各种方法可以实现这款双床目标,但最具吸引力的方式是更好地了解过程和过程参数本身,然后改善和调节它们以获得最佳产量和纯度。这种方法需要快速准确的方法来评估该过程的设计和操作。计算机添加的模拟适合此目的。反过来,这需要一个数学模型,该模型是在系统的声音理论知识或广泛的实验数据的基础上开发的。本文讨论了各种反应建模方法,如平衡恒定方法,吉布斯的自由能最小化和反应动力学。理论建模方法需要具有可靠和准确的物理,化学,热力学和动力学数据。在没有这些数据的情况下,系统可以使用黑盒方法进行模型。还概述了各种实验方法以实现所需的目标

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