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Use of Hydroxy Functional Fluoropolymer Resins in Free Radical UV Curable Coatings

机译:在自由基UV可固化涂料中使用羟基官能含氟聚合物树脂

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Blends of a hydroxy functional fluoropolymer resin with conventional UV curable acrylate diluents were prepared and cured with UV light to form semi-interpenetrating networks (SIPN). After cure the amount of fluoropolymer resin extracted from the films after 5 days with toluene at ambient temperature ranged from 10 to 50 percent of the original amount of the fluoropolymer resin and was proportional to amount of the fluoropolymer resin and was proportional to amount of the fluoropolymer resin in the formulation. Thus, some of the fluoropolymer resin was either physically or chemically incorporated into the crosslinked network. A urethane acrylate oligomer was synthesized from a second hydroxy functional fluoropolymer resin. The oligomer gave good mechanical properties when cured and was compatible with standard acrylate diluents. The cure speed of a model formulation containing the fluoropolymer resin based urethane acrylate oligomer was measured by the modulus ratio at doses of 0.2 and 0.5 J/cm~2 and was found to be 0.9 Environmental stability testing using QUV light and 24 hours of water soaking showed no advantage due to the presence of the fluorine substituted oligomer when compared to a conventional urethane acrylate.
机译:制备具有常规UV可固化丙烯酸酯稀释剂的羟基官能含氟聚合物树脂的混合物并用UV光固化以形成半互穿网络(SIPN)。在固化在5天后在环境温度下在5天后从薄膜中提取的含氟聚合物树脂的量,范围为含氟聚合物树脂的原始量的10-50%,与含氟聚合物树脂的量成比例,与含氟聚合物的量成比例制剂中的树脂。因此,一些含氟聚合物树脂在物理或化学掺入交联网络中。用第二羟基官能含氟聚合物树脂合成氨基甲酸酯丙烯酸酯低聚物。寡聚物在固化时产生良好的机械性能,并与标准丙烯酸酯稀释剂相容。通过0.2和0.5J / cm〜2的剂量比以0.2和0.5J / cm〜2的模量比测量含有含氟聚合物基氨基丙氨酸丙烯酸酯低聚物的模型制剂的固化速度。使用QUV光和24小时的水浸泡,发现为0.9的环境稳定性测试。与常规氨基甲酸酯丙烯酸酯相比,由于存在氟取代的低聚物,没有由于存在而存在的优势。

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  • 来源
    《ACS National Meeting》|2001年||共13页
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    G. K. Noren;

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  • 中图分类 TN252-532;
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