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Effect of magnesium, iron and copper on eutectic solidification of hypoeutectic aluminum-silicon alloys

机译:镁,钢和铜对红氟铝 - 硅合金共晶凝固的影响

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The effect of magnesium, copper and iron on eutectic solidification in hypoeutectic aluminum-silicon foundry alloys of the type A356 and 319 has been investigated. It is found that these elements affect the morphology of the interdendritic eutectic Growth interface. They are therefore also likely to have an effect on the final microstructure, the formation of microporosity and thereby the performance of the casting. The alloys investigated were: pure binary aluminum-silicon alloy, pure aluminum-silicon-magnesium alloy, pure aluminum-silicon-copper alloy, unmodified and strontium modified A356. The samples were directionally solidified with the same solidification conditions (growth rate, thermal gradient and cooling rate). A snapshot of the eutectic growth interface was obtained by quenching the samples during growth. The microstructure of the interface was characterized and the concentrations of different solute elements in the quenched liquid were measured by microprobe analysis. An irregular, flat eutectic growth interface was observed in the binary aluminum-silicon alloy, while the solute added a eutectic mushy zone. The extent of the eutectic mushy zone is dependent on the type and amount of solute added, i.e. a function of segregation tendency. A good correlation was found between the extent of the eutectic mushy zone, the microprobe measurements and phase diagram calculations. It is concluded that the instability of the eutectic growth front is caused by a constitutional undercooling mechanism. Different nucleation mechanisms can occur within the eutectic mushy zone depending on the amount of constitutional undercooling and the potency of nucleating particles.
机译:的镁,铜和铁在所述类型的A356亚共晶铝 - 硅铸造合金和319共晶凝固的影响进行了研究。研究发现,这些元素影响枝晶生长界面的形态。因此,他们也可能对最终组织的作用,微孔的形成,从而使铸件的性能。所研究的合金是:纯二进制铝 - 硅合金,纯的铝 - 硅 - 镁合金,纯铝 - 硅 - 铜合金,未改性的和改性锶A356。将样品定向用相同的凝固条件(生长率,热梯度和冷却速度)固化。通过在生长期间骤冷样品获得的共晶生长界面的快照。界面的微观结构进行了表征,并通过微探针分析测定在淬火液体不同的溶质元素的浓度。在二进制铝 - 硅合金中观察到不规则的,平坦的共晶生长界面,而溶质加入共晶糊状区。共晶糊状区的程度取决于类型和添加溶质的量,即偏析倾向的功能。一个良好的相关性共晶糊状区,微探针测量和相图的计算的程度之间找到。可以得出结论,共晶生长前沿的不稳定性是由成分过冷机制引起的。不同成核机理可以根据成分过冷的量和成核颗粒的效力共晶糊状区内发生。

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