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COPPER RECOVERY FROM SPENT AMMONIACAL ETCHING SOLUTIONS

机译:来自氨氨蚀刻溶液的铜回收

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The extraction of copper using LIX 84-1 was investigated. It was established the extraction isotherm for the system LIX 84-1 (HR = 0.72 M) in Shellsol T/ etching effluent (Cu~(2+) = 121.6 g. L~(-1) NH_4Cl = 4 M and NH_3 = 3 M). The stripping of a loaded organic phase (LIX 84-1 = 0.74 M, Cu~(2+) = 19.9 g.L~(-1)) was carried out with an aqueous solution of sulphuric acid (150 g.L~(-1)) and the stripping isotherm was produced. For both process (extraction and stripping) the number of stages required for an industrial situation was determined. Copper extraction from acidic sulphate solutions using LIX 84-1 was studied in order to define the stoichiometry of copper extraction and to calculate the value of 1.7 for the thermodynamic equilibrium constant.
机译:研究了使用LIX 84-1提取铜。在Shellsol T /蚀刻流出物中建立了系统LiX 84-1(HR = 0.72m)的提取等温线(Cu〜(2+)= 121.6g。L〜(-1)NH_4CL = 4M和NH_3 = 3 m)。用硫酸水溶液进行负载有机相(LiX 84-1 = 0.74m,Cu〜(2+)= 19.9gl〜(-1))的汽提(150gl〜(-1))并且产生了剥离等温线。对于两个过程(提取和剥离),确定工业情况所需的阶段数量。研究了使用LIX 84-1的酸性硫酸盐溶液的铜提取,以定义铜提取的化学计量,并计算热力学平衡常数的1.7的值。

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