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Ferroelectric Soft-Mode Spectroscopy in Disordered Bulk and Thin - Film Perovskites

机译:无序散装和薄膜佩罗夫斯基斯中铁电软模式光谱

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Recent results on the far infrared and microwave spectroscopy of PbTiO_3 -PbZrO_3 system (including PLZT), BaTiO_3 -SrTiO_3 system and PbSc_1/2Ta_1/2O_3 (B-site ordered and disordered) single crystals, ceramics and thin films is reviewed and discussed emphasising also the low-frequency dielectric properties. Generally the soft phonon mode does not soften completely and does not account for the total value of the low-frequency dielectric permittivity. Therefore additional microwave and/or strong radio-frequency dispersion appears, caused by the disorder and/or strong lattice anharmonicities. The thin films show, as a rule, much broader phonon spectra (higher effective soft-mode damping) and smaller low-frequency permittivity compared to the bulk samples. The differences between bulk and htin film behaviour are more pronounced in the (Ba,Sr)TiO_3 system than in the (Pb,La)(Zr,Ti)O_3 system.
机译:最近的结果在PBTIO_3-PBZRO_3系统(包括PLZT)的远红外和微波谱扫描(包括PLZT),BATIO_3 -SRTIO_3系统和PBSC_1 / 2TA_1 / 2O_3(B站有序和混乱)单晶,陶瓷和薄膜也被审查,并讨论了强调低频电介质特性。通常,软主位模式不会完全软化,并且不考虑低频介电介电常数的总值。因此,由疾病和/或强的格子谐波引起的额外微波和/或强射频分散。与批量样品相比,薄膜以规则显示更广泛更广泛的声光谱(更高的有效软模式阻尼)和更小的低频介电常数。体积和HTIN薄膜行为之间的差异在(BA,SR)TIO_3系统中比(PB,LA)(ZR,TI)O_3系统更明显。

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