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Plastic strain effect on the corrosion resistance of continuous hot-dip galvanized steel

机译:塑料应变对连续热浸镀锌钢的耐腐蚀性影响

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Nowadays continuous hot-dip galvanizing is widely used in metallic structures to protect steels against corrosion. Zinc provides a protective barrier thanks to the formation of a surface oxide and a sacrificial protection effect due to its high electroneg-ativity. However, structure manufacturing processes or mechanical assemblies by plastic deformation can create damage affecting the corrosion performance of the coating. The objective of the present work is to study changes of corrosion resistance induced by plastic deformation at room temperature. Uniaxial tensile tests combined with local strain measurements by image correlation were achieved. Specimens were deformed in air at different plastic strain levels. After mechanical tests intergranular cracking was observed by SEM. Electrochemical impedance spectroscopy (EIS) measurements at OCP (Open Circuit Potential) in 0.6M NaCl were performed on unstrained and strained specimens during 15 days. EIS diagrams evolution shows the detrimental effect of plastic deformation on the coating corrosion resistance for high deformation level related to the initial coating damage.
机译:如今,连续热浸镀锌广泛用于金属结构,以保护钢免受腐蚀。由于其高电酮型,锌提供了表面氧化物的形成和牺牲保护效果,提供了保护屏障。然而,结构制造工艺或机械组件通过塑性变形可以产生影响涂层腐蚀性性能的损伤。本作作品的目的是研究室温下塑性变形诱导的耐腐蚀性的变化。实现了通过图像相关性与局部应变测量结合的单轴拉伸试验。标本在不同塑性应变水平的空气中变形。在机械测试后,通过SEM观察晶间裂化。在15天内,在未经测试和应变的样本中对0.6M NaCl中的OCP(开路电位)的电化学阻抗光谱(EIS)测量。 EIS图的演变显示了塑性变形对涂层耐腐蚀性的塑料变形,用于初始涂层损伤的高变形水平。

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