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Effects of Inclusions in HSLA Carbon Steel on Pitting Corrosion in CaCl_2

机译:HSLA碳钢夹杂物对CaCl_2蚀腐蚀的影响

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Susceptibility of high strength low alloy steel to localized corrosion was studied in 6.7 M CaCl_2 for oil and natural gas drilling applications. Results of the immersion and electrochemical experiments showed that the steel is susceptible to pitting corrosion. Optical microscopy investigations of the polished samples revealed that 10% of the surface area was occupied by defects in the form of pits. The energy dispersive X-ray (EDX) and wavelength dispersive X-ray (WDX) chemical analyses revealed higher concentrations of Mn and S compared to the metal matrix in defected areas. These areas served as the sites for development of corrosion pits during both immersion and electrochemical experiments. The fatigue results of the corroded samples indicate that if the pit was the most significant defect, the fatigue crack initiated and propagated at this site.
机译:研究了高强度低合金钢与局部腐蚀的易感性,在6.7M CaCl_2中用于油和天然气钻孔应用。浸没和电化学实验的结果表明,钢易受蚀腐蚀的影响。抛光样品的光学显微镜调查显示,10%的表面积被凹坑形式的缺陷占据。能量分散X射线(EDX)和波长色散X射线(WDX)化学分析显示出与缺陷区域中的金属基质相比较高浓度的Mn和S.这些区域作为在浸没和电化学实验期间开发腐蚀坑的部位。腐蚀样品的疲劳结果表明,如果坑是最显着的缺陷,则在该网站上引发和繁殖的疲劳裂纹。

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