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Heterogeneous catalysis at supercritical conditions using microporous materials. Environmental advantages

机译:使用微孔材料的超临界条件下的异质催化。环境优势

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Supercritical fluids possess uniquie properties that make them attractive as media for chemical reactions. Densities of supercritical fluids are comparable to those of liquids and therefore their dissolving power is high. On the other side diffusion coefficients of components in supercritical fluids are much higher than in liquids. Therefore processes that are mass transfer limited inthe liquid phase, like the majority of heterogeneous catalysed reactions on microporous materials, become faster at supercritical conditions. Supercritical fluids have been potential to replace toxic organic solvents and make reaction processes environmentally friendly. This paper discusses some environmental applications of catalytic reaction processes at supercritical conditions.
机译:超临界流体具有唯一的性质,使其成为化学反应的培养基吸引力。超临界流体的密度与液体的密度相当,因此它们的溶解功率高。在超临界流体中的另一侧扩散系数远高于液体。因此,作为液相的传质有限的方法,如液相,如在微孔材料上的大多数非均相催化反应,在超临界条件下变得更快。超临界流体具有替代有毒有机溶剂并使反应过程环境友好。本文讨论了催化反应过程在超临界条件下的一些环境应用。

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