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Comparing Analytical Results From Different Sources Using Nonidentical Data Sets

机译:使用非识别数据集比较来自不同来源的分析结果

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Industrial corporations frequently require that different analytical facilities or instruments he compared with one another. Traditionally, the isoplot technique is used to accomplish this goal. This technique is only useful, however, when each subject has analyzed a large number of identical samples. Because this is not always the case, the present paper presents an alternate method of comparing analytical results. It is designed for cases where subjects have analyzed a relatively small number of trials from samples that are not identical. The proposed method uses normalized scores and ordinary least squares (OLS) linear regression. In the present case, the proposed method was applied to a situation where the research team compared five different optical emission spectroscopy (OES) laboratories that had tested different sets of OES calibration standards. The normalized scores method provided a quantitative comparison of the laboratories in question. Based on this analysis, it was possible to conclude that one lab (B) clearly lagged behind the others, with respect to the precision of their analyses. It was also apparent that none of the labs were completely accurate. Each either overestimated or underestimated the calibrated element levels.
机译:工业公司经常要求他相互比较的不同的分析设施或仪器。传统上,ISoplot技术用于实现这一目标。然而,当每个受试者分析大量相同的样本时,该技术仅有用。由于这种情况并非总是如此,所以本文提出了比较分析结果的替代方法。它专为受试者分析来自不同的样品数量的案例而非相同的情况。该方法使用归一化分数和普通最小二乘(OLS)线性回归。在本案例中,该方法应用于研究团队比较五种不同的光学发射光谱(OES)实验室的情况,这些情况已经测试了不同组的OES校准标准。标准化的分数方法提供了有问题的实验室的定量比较。基于此分析,可以得出结论,一个实验室(b)在其分析的精确度方面明显落后于其他实验室。显而易见的是,没有一个实验室完全准确。每个都高估或低估校准元素水平。

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