首页> 外文会议>Symposium on materials for electrochemical energy storage and conversion II-Batteries, capacitors and fuel cells >The corrosion phenomena in the coin cell BR2325 of the 'superstoichometric fluorocarbon-lithium' system
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The corrosion phenomena in the coin cell BR2325 of the 'superstoichometric fluorocarbon-lithium' system

机译:“超级体氟碳 - 锂”系统的硬币细胞BR2325中的腐蚀现象

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It was noted at the earlier study and at the longer observations of the novel various types of superstoichiometric fluorocarbon materials CF_(1+x), where x chemical bounds 0.1-0.33 (FCM) and their behavior, that depsite of their known hygroscopity during a storage of samples in laboratory and technological utensils nevertheless occurs an appreciable sorption of atmospheric moisture. The color of samples does not change but sometimes there is appears a smell of hydrogen fluoride and even corrsoion of glasswares at a long storage. On the basis of these facts was assumed that at a long storage the slow reactions of HF producing with a sorption moisture can proceed. This phenomena is necessary to take into account for successful manufacuturing of long life lithium cells based on superstoichiometric fluorcarbon composite composite cathodes (FCC).
机译:它在早期的研究中指出,并且在新颖的各种类型的超细管碳氟碳材料CF_(1 + X)的较长观察中,其中x化学界限为0.1-0.33(FCM)及其行为,即其所知的吸湿性物质的STEM然而,在实验室和技术用具中的存储仍然发生了大气湿度的可观吸附。样品的颜色不会改变,但有时出现氟化氢的气味,甚至在长储存时均匀的玻璃纤维。在这些事实的基础上,假设在长时间储存​​时,HF产生吸附水分的缓慢反应可以进行。必须考虑基于超细管氟碳复合复合阴极(FCC)的长寿命锂电池的成功制造方法所必需的这种现象。

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