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An Innovative Process for Extracting Scandium from Nickeliferous Laterite Ore

机译:从硝酸盐中提取钪的创新过程

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Laterite ores contain significant amounts of scandium, a strategic material with versatile applications. In this study, a two-stage process was developed to concentrate and recover scandium from nickeliferous laterite ore. In the first step, carbothermic smelting was performed at 1400-1600 °C using lignite as a reductant and calcia and/or silica as a flux. This process resulted in a slag phase concentrated in Sc and a metallic iron phase enriched with nickel and cobalt. Under the optimum conditions, scandium was successfully concentrated in the slag phase more than 14 times than that in the starting material. In the second step, the slag phase was leached using NaOH cracking to recover Sc. A fractional factorial design methodology was utilized to investigate the effect of various operating parameters during the smelting and the leaching processes and to optimize the processes. After optimization, 88% of scandium was recovered during the NaOH cracking process.
机译:红土矿石含有大量的钪,具有多功能应用的战略材料。在这项研究中,开发了一种两阶段的方法来浓缩和从乳酸后矿石中储存钪。在第一步中,使用褐煤作为还原剂和钙质和/或二氧化硅作为助焊剂在1400-1600℃下进行Carbothotmic冶炼。该方法导致浓缩的渣相和富含镍和钴的金属铁相。在最佳条件下,钪在渣阶段成功集中于比原料中的14倍以上。在第二步中,使用NaOH裂解浸出炉渣相以回收Sc。利用分数阶乘设计方法来研究各种操作参数在冶炼过程中的效果和浸出过程,并优化过程。优化后,在NaOH开裂过程中回收了88%的钪。

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