Effects of Reaction Conditions on Hydrogen Production of Fe Complexes Catalyst in Photocatalysis System

摘要

Fe thiolate complexes Fe(bpy)(pyS)_2 (M) were synthesized, the properties of complexes were characterized by ~1H-NMR and MS and the effects of reaction conditions on catalytic performance had been studied. The results of catalytic performance implied that when 5% triethylamine was used as electron donor, 2.0 mM fluoresce in was used as photo sensitizer and the catalyst content was 2.5 μM, the hydrogen production of M reached 89.6 μmol/h after reacted for 15 hours.