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Synthesis of 1,5,6,10-Tetranitrodecahydro-1,4 Diazepino 2,3-b Diazepine and Its Thermal Property Research

机译:合成1,5,6,10-四腈二苯并羟基羟基羟基苯并羟基苯并羟基氨基2,3-B二氮杂化及其热性质研究

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1,5,6,10-tetranitrodecahydro-[1,4] diazepino [2,3-b] diazepine(TNDP)was synthesized using tetranitroglycoluril as the starting material by hydrolysis reaction and condensation.The thermo stability of TNDP was studied by DSC and TG-DTA methods,and the thermodynamic parameters were calculated by Kissinger method and related formulas.The results showed that TNDP was thermal stable and the peak temperature of DSC was 311.76 °C.The apparent activation energy was 162.70 kJ/mol.In general,TNDP is a kind of good performance energetic materials.
机译:通过水解反应和缩合使用四硝基毒液作为原料合成1,5,6,10-四硝基替哌啶唑(TN23-B]二氮杂肠(TNDP)。通过DSC研究TNDP的热稳定性通过基辛格方法和相关公式计算热力学参数和热力学参数。结果表明TNDP是热稳定的,DSC的峰值温度为311.76°C。明显的活化能量为162.70 kJ / mol.in将军,TNDP是一种良好的性能能量材料。

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