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Preparation and Application of PoIy(Acrylic Acid-co-Acrylamide) on Scale and Corrosion Inhibition

机译:POIY(丙烯酸 - 共丙烯酰胺)对规模和腐蚀抑制的制备及应用

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This research is focused on the synthesis and the ability to inhibit scale and corrosion of poly(acrylic acid-co-acrylamide) (PAA-AM copolymers). A series of polymers were synthesized by free radical polymerization having various weight ratios of acrylic acid (AA) to acrylamide (AM). The structures of the synthesized polymers were characterized by UV-Vis Spectroscopy, FT-IR, and ~1H-NMR. The thermal stability of the polymers was analyzed by a TGA technique. The water solubility of the polymers was examined using a turbidity meter. The scale inhibition performance test was performed by titration of calcium ion with ethylene diamine tetraacetic acid (EDTA) solution. After that, the crystal structure of CaCO_3 scale from the scale inhibition test was examined using a scanning electron microscope. The efficiency of the corrosion inhibitor on low carbon steel AISI 1018 was investigated by a potentiodynamic polarization technique. The result show that PAA-AM copolymers having a 9:1 weight ratio with 45.82% at 100 ppm inhibited scale forming. The corrosion resistance of all inhibitors could be achieved when the concentration of the inhibitor was lower than 100 ppm.
机译:该研究专注于合成和抑制聚(丙烯酸 - 共聚物)(PAA-AM共聚物)的规模和腐蚀的能力。通过具有各种重量比丙烯酸(AA)至丙烯酰胺(AM)的自由基聚合来合成一系列聚合物。通过UV-Vis光谱,FT-IR和〜1H-NMR的特征在于合成聚合物的结构。通过TGA技术分析聚合物的热稳定性。使用浊度计检查聚合物的水溶性。通过用乙二胺四乙酸(EDTA)溶液滴定钙离子来进行规模抑制性能试验。之后,使用扫描电子显微镜检查从比例抑制试验的Caco_3刻度的晶体结构。采用电位偏振技术研究了腐蚀抑制剂对低碳AISI 1018的效率。结果表明,PAA-AM共聚物具有9:1重量比,其100ppm抑制尺度形成为45.82%。当抑制剂的浓度低于100ppm时,可以实现所有抑制剂的耐腐蚀性。

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