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Simple approach in understanding interzeolite transformations using ring building units

机译:使用环形建筑单位了解Interzeolite转换的简单方法

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Recently, there are two general approaches used in understanding interzeolite transformations, thermodynamically represented by framework density (FD) and kinetically by structural building units. Two types of structural building units are composite building units (CBU's) and secondary building units (SBU's). This study aims to examine the approaches by using interzeolite transformation data available in literature and propose a possible alternative approach. From a number of cases of zeolite transformation, the FD and CBU approach are not suitable for use. The FD approach fails in cases involving zeolite parents that have moderate or high FD's, while CBU approach fails because of CBU's unavailability in parent zeolites compared with CBU's in their transformation products. The SBU approach is most likely to fit because SBU's are units that have basic form of ring structures and closer to the state and shape of oligomeric fragments present in zeolite synthesis or dissolution cases. Thus, a new approach can be considered in understanding the interzeolite transformation, namely the ring building unit (RBU) approach. The advantage of RBU approach is RBU's can be easily derived from all framework types, but in SBU approach there are several types of frameworks that cannot be expressed in SBU forms.
机译:最近,有两种通用方法用于了解Interzeolite转换,通过框架密度(FD)和通过结构构建单元动力学地表示。两种类型的结构构建单位是复合建筑单位(CBU的)和二级建筑单位(SBU)。本研究旨在通过使用文献中提供的透明石转换数据来检查方法,并提出可能的替代方法。从沸石转化的许多情况下,FD和CBU方法不适合使用。在涉及中等或高FD的沸石父母的情况下,FD方法失败,而CBU方法由于CBU在父沸石中的不可用而与其转换产品中的CBU相比,因此CBU方法失败。 SBU方法最有可能适合,因为SBU是具有环形结构的基本形式的单位,并且更接近沸石合成或溶出病例的寡聚片段的状态和形状。因此,可以考虑一种在理解透明石变换时,即环形建筑单元(RBU)方法。 RBU方法的优点是RBU可以容易地从所有框架类型中派生,但在SBU方法中,有几种类型的框架不能以SBU形式表达。

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