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Effect of Activated Alkanolamine for CO2 Absorption using Hollow Fiber Membrane Contactor

机译:活性链烷醇胺对中空纤维膜接触器的CO2吸收的影响

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Hollow Fiber Membrane Contactor (HFMC) technology has been widely developed as an alternative technology to separate CO2 gas. HFMC technology combines gas absorption process with absorbent and membrane technology. Membrane contactor technology has advantages than conventional technology such as larger gas-liquid contact area, smaller equipment, modularity, and gas-liquid flow rates adjusted independently. In this research, the CO2 absorption experiments was conducted for absorption process at 30°C temperature and various gas flow rate from 200 - 600 mL/min, feed gas of CO2 20%vol. flowed into shell side and the absorbents flowed in tube side of membrane contactor. Piperazine (PZ) and monosodium glutamate (MSG) as activators with l%w/w concentration, added into methyldiethanolamine (MDEA) 30% w/w solution to form aqueous solutions of activated MDEA. The membrane material used in this experiment was hydrophobic polypropylene membrane. The effect of liquid flow rate and various activators used to get CO2 absorption flux and CO2 removal in HFMC. The results showed that the best of CO2 absorption process using activated alkanolamine was MDEA-PZ, where the highest flux value was 5.5x10~(-4) mole/m~2.s and CO2 removal reached 96.9% at a gas flow rate of 600mL/min.
机译:中空纤维膜接触器(HFMC)技术已被广泛开发为替代技术,以分离CO2气体。 HFMC技术将气体吸收过程与吸收剂和膜技术相结合。膜接触器技术具有比传统技术的优点,如较大的气液接触面积,较小的设备,模块化和气液流速独立调整。在该研究中,在30℃的温度下进行CO 2吸收实验,在200 - 600mL / min的各种气体流速下进行吸收过程,CO 2 20%Vol的进料气体。流入壳体侧,吸收剂在膜接触器的管侧流动。哌嗪(PZ)和谷氨酸钠(MSG)作为具有L%W / W浓度的活化剂,加入甲基二乙醇胺(MDEA)30%w / w溶液中以形成活性MDEA的水溶液。本实验中使用的膜材料是疏水性聚丙烯膜。液体流速和各种活化剂用于在HFMC中获得CO 2吸收通量和CO 2的影响。结果表明,使用活性链烷醇胺的最佳二氧化碳吸收过程是MDEA-PZ,其中最高助焊剂值为5.5×10〜(-4)摩尔/ m〜2.s,CO 2在气体流速下达到96.9% 600ml / min。

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