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Electrochemical Oxidation of Two Phenolic Compounds: Evaluation of Kinetics and Energy Consumption

机译:两种酚类化合物的电化学氧化:动力学和能耗评估

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Bisphenol A (BPA) and p-cresol are two phenolic compounds present in industrial wastewater and they are harmful to the environment. Electrochemical oxidation is a technology that has the ease of coupling to other treatment systems and is environmentally friendly. In this study, electrochemical oxidation of 100 mg/L of BPA and 50 mg/L of p-cresol were tasted using Boron Doped diamond (BDD) anodes. The results aim that the pseudo-first order kinetic constants (k) had the same order of magnitude for both compounds. Slightly higher values of k were obtained when using a J of 250 A/m~2 than other conditions, removing the pollutants in less than 120 min; while the mineralization was completed around 240 and 210 min, respectively. To compare the energy consumption, the parameter Electrical Energy per Order was used, obtaining that to eliminate 90% of the compounds it is required between 6-8 kW·h/m~3·order and 60 kW-h/m~3·order for the mineralization.
机译:双酚A(BPA)和P-甲酚是产业废水中存在的两种酚类化合物,它们对环境有害。电化学氧化是一种技术,可以易于耦合到其他治疗系统并环境友好。在该研究中,使用硼掺杂的金刚石(BDD)阳极品尝100mg / L的BPA和50mg / L的P甲酚的电化学氧化。结果目的是伪第一阶动力学常数(K)对两种化合物具有相同的数量级。当使用比其他条件的250A / m〜2的J为250 A / m〜2时,获得稍微较高的k值,从而在小于120分钟的污染物中除去污染物;虽然矿化分别在240%和210分钟内完成。为了比较能量消耗,使用每个顺序的参数电能,从而获得以消除90%的化合物,在6-8 kW·h / m〜3·订单和60 kW-h / m〜3·矿化的顺序。

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