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A light olefin selective FCC catalyst based on Ti,Zr-inserted USY zeolite

机译:基于Ti,Zr插入的USY沸石的轻烯烃选择性FCC催化剂

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Following the successful commercial deployment of the CAN-15 hydrocracking catalyst at Saudi Aramco’s Riyadh Refinery,the collaborating teams from Aramco R&DC and Japanese JGC C&C developed a new light olefin selective FCC catalyst based on a newly developed USY zeolite.The catalyst,labelled as CAN-FCC3,was tested in a lab scale ACE reactor for converting hydrocracking bottom(HCB)feedstock to light olefins,especially propylene and butenes,at the FCC Laboratory of KFUPM under a technical laboratory services agreement.Two sets of parallel tests on CAN-FCC3 were administered:(1] cracking catalyst only mode in comparison with a JGC C&C’s standard FCC catalyst and [2] cracking catalyst with olefin additive mode in comparison with a top-tier olefin-selective FCC catalyst from another catalyst vendor.The cracking activity of CAN-FCC3 catalyst was found to be similar to that of JGC C&C’s standard FCC catalyst,but CAN-FCC3 was more selective in producing naphtha range olefins from the HCB feed.When a JGC C&C’s proprietary olefin additive was included in the ACE testing at 10 wt.% of the catalyst load of CAN-FCC3,the combined light olefins(C2~=-C4~=)yield reached 54%(26.7%-propylene alone] in comparison with 40.6%(17.7%-propylene alone)of the test run with the top-tier olefin-selective vendor catalyst,which contains 10 wt.% olefin additive in the catalyst formulation.
机译:在Saudi Aramco的利雅得炼油厂成功的Can-15加氢裂化催化剂的商业部署之后,来自Aramco R&DC和日本JGC C&C的合作团队在新开发的USY沸石上开发了一种新的轻烯烃选择性FCC催化剂。催化剂,标记为CAN -fcc3在实验室标度Ace反应器中测试,用于将加氢裂化底部(HCB)原料转化为轻烯烃,尤其是丙烯和丁烯,在KFupm的FCC实验室,在技术实验室服务协议下。罐头FCC3上的并联试验集合施用:(1]裂化催化剂的催化剂与JGC C&C的标准FCC催化剂和[2]裂化催化剂与烯烃添加剂模式相比,与来自另一种催化剂供应商的顶层烯烃选择性FCC催化剂相比。裂化活性发现CAN-FCC3催化剂与JGC C&C的标准FCC催化剂类似,但CAN-FCC3在从HCB饲料中产生石脑油烯烃的选择性更具选择性。当JGC C&C的专有烯烃添加剂包含在10重量%的ACE测试中。罐-FCC3的催化剂负荷的%,组合的光烯烃(C2〜= -C4〜=)产率达到54%(仅为26.7% - 丙烯)相比之下,用顶层烯烃选择性供应商催化剂的试验与含有10重量%的烯烃添加剂在催化剂配方中的40.6%(17.7% - 单独)。

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