Injection moldable thermoplastic polyurethanes (TPUs) have been used in golf ball cover layers since the 1980s and can provide an attractive combination of formulation flexibility, performance, ease of processing, and overall lower cost when compared to cast thermoset polyurethane and polyurethane-urea systems. In developing raw material specifications for TPU and in their polymerization at the material supplier, melt flow index (MFI) is often used as a means to target certain processing and property requirements. However, using MFI as the only metric for quantifying a given TPU formulation can lead to problems as it does not capture polymerization and thermal history dependent structural variations inherent to these materials. In this study, final golf ball performance attributes, mechanical properties, thermal properties, dynamic mechanical properties, and dynamic rheological properties of two batches of TPU with identical composition and MFI were compared and contrasted. The results will be used to illustrate why TPU copolymer segmental structure and both temperature and time dependent morphology are important in the processing characteristics and properties of these versatile materials.
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