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Thermo-expandable Microcapsule as a Blowing Agent for Producing Thermoplastic Elastomer Vulcanized Syntactic Foam

机译:热可扩展的微胶囊作为生产热塑性弹性体硫化局部泡沫的发泡剂

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Thermoplastic Elastomer Vulcanized (TPE-V) syntactic foams made by Thermo-Expandable Microcapsules (TEMs) are becoming of a large interest for automotive industry. TPE-Vs combine advantages of class rubber compound properties with an easier manufacture process and are recyclable. Therefore, TPE-Vs are more and more used to manufacture automotive sealing system by an extrusion process, which is the focus of this research. Due to the two-phase structure of TPE-V, classical extrusion foaming technologies, such as chemical and physical foaming, are complex to be controlled. Thus, TEMs show an outstanding ability to be effective and produce repeatable micro structure with standard extrusion equipment. TEMs consist in a mixture of liquid hydrocarbons, encapsulated by a gas-proof polymeric shell. Exposed to elevated temperatures, the internal pressure drives the dilation of the TEMs, as a result a TPE-V syntactic foam is produced. The aim of this study is to understand where the expansion occurs and how can it be affected by extrusion process parameters. Temperature is a well-known key parameter to control final expansion of TEMs. Hence, measurements at high pressure and temperature were done to find out the location of expansion during extrusion process. Additionally, we have designed three groups of three dies to apply different pressure drops, pressure drop rates and residence time, inside the die. Under these process conditions, density, cell micro structure and viscosity have been investigated.
机译:热塑性弹性体硫化(TPE-V)通过热膨胀微胶囊制成的句法泡沫(TEMS)对汽车行业进行了很大的兴趣。 TPE-VS将橡胶复合性能的优点与更容易制造的工艺相结合,可回收。因此,TPE-VS越来越多地用于通过挤出过程制造汽车密封系统,这是该研究的重点。由于TPE-V的两相结构,典型的挤出发泡技术,例如化学和物理发泡,是可控制的。因此,TEMS显示出具有有效的能力,并用标准挤出设备生产可重复的微结构。 TEM在液体烃的混合物中由防毒聚合物壳包封。暴露于升高的温度,内部压力驱动TEM的扩张,结果产生TPE-V局部泡沫。本研究的目的是了解膨胀发生的位置,并且如何受挤出过程参数的影响。温度是一个众所周知的关键参数,可控制TEM的最终扩展。因此,在高压和温度下进行测量以在挤出过程中找出膨胀位置。此外,我们设计了三组三个模具,以施加不同的压降,压降率和停留时间,在模具中。在这些过程条件下,已经研究了密度,细胞微结构和粘度。

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