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Electrochemical Characterization of Conductive Hybrid Coatings Obtained for Protection against Corrosion of Carbon Steel

机译:碳钢腐蚀保护的导电杂化涂层的电化学特征

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Conductive hybrid coatings are an alternative for the production of multifunctional coatings, enabling wide application in industry for metal surface finishing. Recently, the use of pretreatments using the sol-gel process has become an attractive area of study, due to its high efficacy against corrosion, low cost and easy application. Among the conducting polymers used as corrosion inhibitors there is polyaniline. The method of mixing in solution is based in the solubility of PAni in solvents with counter-ions used to dope it. The redoped state of PAni with functionalized organic acids improves its thermal stability and processability. In this work, the aim is to synthesize and characterize a solution of precursor sol-gel P(MMA-MSMA)-TEOS, poly(methyl methacrylate co-3-(trimethoxysilyl)propyl methacrylate) and tetraethyl orthosilicate with the introduction of PAni solution in sol-gel. To evaluate the corrosion resistance of conductive hybrids, electrochemical techniques of open circuit potential with time, electrochemical impedance spectroscopy (EIS) and polarization curves were used.
机译:导电杂交涂层是生产多功能涂层的替代方案,使得在工业方面适用于金属表面精加工。最近,使用溶胶 - 凝胶工艺的预处理已成为一种有吸引力的研究领域,因为它具有抗腐蚀,低成本和易于应用的高效力。在用作腐蚀抑制剂的导电聚合物中,存在聚苯胺。在溶液中混合方法是基于PANI在溶剂中的溶解度,其用于掺杂的抗衡离子。具有官能化有机酸的PANI的重新转化状态可提高其热稳定性和加工性。在这项工作中,目的是合成和表征前体溶胶 - 凝胶P(MMA-MSMA)-TeOS的溶液,聚(甲基丙烯酸甲酯CO-3-(三甲氧基甲硅烷基)丙基甲基丙烯酸丙酯)和甲基丙烯酸四乙基硅酸酯,引入PANI溶液在溶胶 - 凝胶中。为了评估导电混合动力车的耐腐蚀性,使用具有时间的开路电位的电化学技术,电化学阻抗光谱(EIS)和偏振曲线。

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