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Adsorption of Ni(II) ions from aqueous solution on the DMSA functionalized magnetic nanoadsorbents

机译:将Ni(II)离子从水溶液中吸附在DMSA官能化磁纳米坯料中

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The magnetic nanoparticles (MNPs) were synthesized by the thermal decomposition method and functionalized with meso-2,3-dimercaptosuccinic acid (DMSA). The MNP-DMSA were used as a nanoadsorbents for the removal of Ni(II) ions from aqueous solution. MNPs were characterized by X-ray diffraction (XRD), field emissionscanning electron microscopy (FESEM), and vibrating sample magnetometer (VSM). The MNPs have magnetite phase with a particle size around 25 nm. The magnetic measurement showed that MNPs exhibits superparamagnetic nature with a saturation magnetization of 44 emu/g. The batch adsorption experiments were carried out to remove Ni(II) by optimizing the contact time and initial Ni(II) concentration. The maximum 60 % efficiency was achieved for Ni(II) metal ions removal from the aqueous solution.
机译:通过热分解方法合成磁性纳米颗粒(MNP)并用Meso-2,3-二巯基琥珀酸(DMSA)官能化。 MNP-DMSA用作纳米坯料,用于从水溶液中除去Ni(II)离子。 通过X射线衍射(XRD),现场发射丙烷电子显微镜(FESEM)和振动样品磁力计(VSM)的表征为MNP。 MNP具有粒径为约25nm的磁铁矿相。 磁性测量表明,MNPS表现出具有44 emu / g的饱和磁化强度的超顺磁性。 通过优化接触时间和初始Ni(II)浓度来进行批量吸附实验以除去Ni(II)。 Ni(II)金属离子从水溶液中除去的最大60%效率。

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