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Flow behaviour of a model colloid-polymer mixture using mode-coupling theory

机译:模型胶体聚合物混合物使用模式耦合理论的流动性能

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The nonlinear rheology of a model colloid-polymer mixture is investigated by considering a square-wellsystem (SWS). The dynamics of the system under a constant shear rate is theoretically simulated using the mode-coupling theory of glass transition (MCT) within integration through transientsframework (ITT). The state of the SWS can be controlled by tuning three control parameters: packing fraction, attraction range and attraction strength. MCT predicts three distinct phases: liquid, repulsive glass, and attractive glass for the SWS based on these three parameters. Apart from regular liquid-glass transition lines, MCT also predicts higher-order singularities in the phase diagram. The current work discusses the stress-strain relationship and flowcurves around one such singularity called as swallow-tail singularity or A_4 singularity. It is observed that though the density correlators have been observed to change around this singularity, there is no noticeable effect of this singularity on rheological properties of the SWS or colloid-polymer mixture.
机译:通过考虑方形 - Wellsystem(SWS)来研究模型胶体聚合物混合物的非线性流变学。在通过TransientFramework(ITT)的集成中,理论上模拟系统下的系统的动态在理论上模拟了玻璃转换(MCT)。可以通过调整三个控制参数来控制SWS的状态:包装分数,吸引范围和吸引力。 MCT预测三个不同的阶段:基于这三个参数的SWS的液体,排斥玻璃和具有吸引力的玻璃。除常规液体玻璃过渡线外,MCT还预测相图中的高阶奇点。目前的工作讨论了一个称为燕尾奇异性或A_4奇点的一个如此奇点的应力 - 应变关系和流量。观察到,虽然已经观察到密度的相关剂围绕这种奇点改变,但这种奇点对SWS或胶体 - 聚合物混合物的流变性质没有明显的影响。

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