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Crystallite size strain analysis of nanocrystalline La_(0.7)Sr_(0.3)MnO_3 perovskite by Williamson-Hall plot method

机译:基于纳米霍尔 - 霍尔幽灵局部法的纳米晶LA_(0.7)SR_(0.3)MNO_3钙钛矿的微晶尺寸应变分析

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The nanocrystalline Sr-doped LaMnO_3 (La_(0.7)Sr_(0.3)MnO_3 = LSMO) perovskite manganites having different crystallite size were synthesized using the nitrate-glycine auto-combustion method. The phase purity of the manganites was checked by X-ray diffraction (XRD) measurement. The XRD patterns of the sample reveal that La_(0.7)S_(0.3)MnO_3 crystallizes into rhombohedral crystal structure with space group R-3c. The size-dependence of structural lattice parameters have been investigated with the help of Rietveld refinement. The structural parameters increase as a function of crystallite size. The crystallite-size and internal strain as a function of crystallite-size have been calculated using Williamson-Hall plot.
机译:使用硝酸甘油自燃方法合成具有不同微晶尺寸的纳米晶体Sr掺杂的兰诺-3(La_(0.7)Sr_(0.3)MnO_3 = LSMO)钙钛矿锰酸盐。通过X射线衍射(XRD)测量检查锰酯的相纯度。样品的XRD图案显示La_(0.7)S_(0.3)MnO_3与空间组R-3C结晶到菱形晶体结构中。在RIETVELD改进的帮助下已经研究了结构格子参数的尺寸依赖性。结构参数随着晶体尺寸的函数而增加。使用Williamson-Hall Plot计算了作为微晶尺寸的函数的微晶尺寸和内部菌株。

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