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Investigation On Structural, Optical And Magnetic Properties Of Double Perovskite Gd_2NiMnO_6

机译:双钙钛矿GD_2NIMNO_6结构,光学和磁性的研究

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Single phase double perovskite Gd_2NiMnO_6 was prepared by conventional solid state reaction route. X-ray diffraction (XRD) result reveals that the compound possess monoclinic structure with space group P2_1/n. Optical characterization performed at room temperature via UV-visible spectroscopy confirms Gd_2NiMnO_6 as a direct band-gap material with band gap of ~1.5 eV. Magnetization measurement in Zero field cooled (ZFC) condition at H = 100 Oe shows magnetic transition at ~125 K. Due to competing interactions between magnetic ions (Ni~(2+) and Mn~(4+)), we could observe two magnetic transition below 40 K.
机译:通过常规固态反应途径制备单相双钙钛矿GD_2NIMNO_6。 X射线衍射(XRD)结果表明,该化合物具有空间组P2_1 / N的单斜晶结构。通过UV可见光谱在室温下在室温下进行光学表征,证实GD_2NIMNO_6作为具有〜1.5eV的带隙的直接带间隙材料。 H = 100 OE的零场冷却(ZFC)条件下的磁化测量显示磁性过渡在〜125k.由于磁离子(Ni〜(2+)和Mn〜(4+)之间的竞争相互作用,我们可以观察到两个磁过渡到40 k下方。

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