Water Vapour Sorption and Hysteresis Models Applicable for Silicate Building Materials

摘要

Various models of the water vapour sorption isotherms were analysed from the aspect of their applicability for silicate-based building materials like calcium-silicates, burnt clay bricks, plasters and mortars. The analysis included the assessment of the various sorption hysteresis models. They were compared and calibrated with experimental data, consisting of the main adsorption and the scanning curves. For the silicate-based building materials as a fundamental the Brunauer–Emmett–Teller (BET) and Frenkel–Halsey–Hill (FHH) models of adsorption in a combination together with Kelvin-Cohan (KC) model of desorption, with the Independent Domain Model of hysteresis can be applied due to their satisfactory universality.