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Application of ISCO to Petroleum Hydrocarbon-Impacted Soil at a South San Francisco LUST Site

机译:ISCO在南旧金山欲望部位施用土壤的石油碳氢化合物土壤

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The Site is located in South San Francisco, California, and is currently used for rental car fleet parking and fueling. Impact to soil from gasoline and diesel fuel was detected during a UST removal and replacement in 2003. Investigations were conducted to characterize the magnitude and extent of petroleum hydrocarbon impact to soil at the Site which indicated that total petroleum hydrocarbons (TPH) as gasoline and diesel, and the fuel components benzene, toluene, ethylbenzene, xylenes (BTEX) and methyl-tert-butyl ether (MTBE), were present in soil at concentrations exceeding the Environmental Screening Levels (ESLs). Most of the impact was primarily limited to an approximate 15 foot diameter zone around the fuel dispensers. Tetra Tech selected use of an in situ chemical oxidation compound (ISCO) as the most feasible remedy for impacted soil at the Site. ISCO was injected into subsurface soil at the Site in three applications between July 2007 and March 2008. Baseline soil sampling was conducted prior to ISCO injection, and confirmation soil sampling was conducted following each ISCO injection event. Post injection BTEX and MTBE concentrations declined below the respective ESL values. In 2009, two sub-slab soil gas samples were collected from the fill material beneath the adjacent building. The soil gas samples were analyzed for TPH as gasoline and diesel, benzene, and MTBE. Analytical results indicate that TPH as gasoline and diesel were not detected at concentrations at or above the laboratory reporting limits. Benzene and MTBE were detected in sub-slab soil gas samples, but at concentrations below the respective soil gas ESL values. The Site has received preliminary closure.
机译:网站位于南旧金山,加利福尼亚州,目前用于出租的车队停车加油。一个UST移除和更换在2003年的调查过程中检测到从汽油和柴油燃料冲击到土壤进行了在这表明总石油烃(TPH)汽油和柴油站点到的大小和石油烃影响程度表征土壤和燃料组件苯,甲苯,乙苯,二甲苯(BTEX)和甲基叔丁基醚(MTBE),存在于土壤浓度超过环境筛选级别(电子货架标签)。大部分的影响主要限于围绕燃油加油机大约15英尺直径的区域。利技术选择使用的原位化学氧化化合物(ISCO)作为用于在工地影响土壤最可行的补救措施。 ISCO在网站中三个应用程序2007年7月和2008年3月基线土壤取样之间注入到地下土壤ISCO注射前进行,并确认土壤取样,每个ISCO注射事件后进行的。后喷射BTEX和MTBE的浓度下降低于各自ESL值。在2009年,两个子板土壤气体样品从相邻建筑物之下的填充材料收集。土壤气体分析样品的TPH如汽油和柴油,苯,和MTBE。分析结果表明,TPH为未在等于或高于实验室报告范围的浓度检测到汽油和柴油。苯和MTBE子板土壤气体样品中检测到,但在低于各自的土壤气体ESL值浓度。该网站已经获得初步闭合。

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