Electrospray Ionisation Mass Spectrometry for the Complexation of Palladium with Thiourea, Benzoylthiourea and N,N-diethyl N'-benzoylthourea

摘要

ESI-MS studies were carried out to compare the behavior of Pd complexes with thiourea and two of its derivatives viz. BTU and DEBT. Preferential bidentate coordination mode of DEBT compared to BTU and TU was observed. The Pd (DEBT)2 complex was found to be more stable compared to Pd(TU)2 and Pd(BTU)2 under the conditions employed.