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Ion Source for Doping of Superfluid Helium Nanodroplets by a High Flux of Low Kinetic Energy Alkali Cations

机译:通过高通量碱阳离子的高通量掺杂超氟氦纳米辊的离子源

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Currently, our group is working to introduce ions into superfluid helium nanodroplets for complexation with neutral molecules. In a helium nanodroplet, an alkali cation may form a complex with any neutral molecule, allowing for the possibility of mass spectrometry without fragmentation, or high resolution infrared spectroscopy. To introduce alkali cations into helium nanodroplets low energy ions are focused into the helium nanodroplet beam path where they may be solvated by a droplet and detected. Previous sources used for this experiment consisted of wire filaments coated with a molecular sieve paste which had been saturated with an alkali metal salt. These sources had the ability to produce low energy ions, but could not produce large currents due to the limitations of using a doped filament. The achievement of higher ion currents of low energy alkali cations required the design of a custom built ion source.
机译:目前,我们的小组正在努力将离子引入超流氦纳米杆,以与中性分子络合。在氦纳米杆上,碱阳离子可以形成与任何中性分子的复合物,允许没有碎片化的质谱或高分辨率红外光谱的可能性。为了将碱性阳离子引入氦纳米杆纳米粒子中,低能量离子聚焦到氦纳米射线束路径中,在那里它们可以通过液滴溶剂溶液并检测到。用于该实验的先前来源由涂有含有碱金属盐饱和的分子筛浆料的线束组成。这些来源具有产生低能量离子的能力,但由于使用掺杂灯丝的局限性而不能产生大的电流。低能量碱阳离子的更高离子电流的实现需要定制内置离子源的设计。

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